JAMB & WAEC Chemistry & Physics: Stoichiometry, Gas Laws, Electrochemistry, Organic Chemistry, Mechanics, Waves, Electricity & Atomic Physics
Covers JAMB UTME & WAEC WASSCE Chemistry and Physics: Separation Techniques, Gas Laws, Periodic Table, Electrolysis (Faraday's Laws), Industrial Processes (Haber, Contact, Frasch), Organic Functional Groups, Kinematics, Projectile Motion, Simple Machines, Optics, Waves, Electricity, and Radioactivity.
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- JAMB & WAEC Chemistry & Physics: Stoichiometry, Gas Laws, Electrochemistry, Organic Chemistry, Mechanics, Waves, Electricity & Atomic Physics (.md)
Flashcards (32)
| # | Front (Term / Question) | Back (Definition / Answer) | Example | Multiple-Choice Options |
|---|---|---|---|---|
| 1 | In JAMB/WAEC Acid-Base Titration, which indicator is suitable for: (a) Strong Acid + Strong Base, (b) Strong Acid + Weak Base, and (c) Weak Acid + Strong Base? | (a) Strong Acid + Strong Base (e.g., HCl + NaOH): Any indicator (Methyl orange or Phenolphthalein); (b) Strong Acid + Weak Base (e.g., HCl + NH3/Na2CO3): Methyl orange; (c) Weak Acid + Strong Base (e.g., CH3COOH or H2C2O4 + NaOH): Phenolphthalein. | ||
| 2 | In JAMB/WAEC Sound Waves (Pipes & Strings), what are the fundamental frequency (f0) and harmonics produced by a Closed Pipe of length L versus an Open Pipe or Stretched String of length L? | Closed pipe (node at closed end, antinode at open end, L = λ/4): f0 = v / (4L), producing ONLY odd harmonics (f0, 3f0, 5f0...). Open pipe or stretched string (L = λ/2): f0 = v / (2L), producing ALL harmonics—both odd and even (f0, 2f0, 3f0...). | ||
| 3 | In JAMB/WAEC Waves, what is the fundamental wave equation, and which wave properties distinguish Longitudinal waves from Transverse waves? | Wave speed v = fλ (where f is frequency in Hz and λ is wavelength in m). Only Transverse waves (light, electromagnetic waves, water/string waves) can be POLARIZED because their vibrations are perpendicular to the direction of wave propagation; Longitudinal waves (sound waves) vibrate parallel to propagation and cannot be polarized. | ||
| 4 | In JAMB/WAEC Thermal Physics, distinguish between Specific Heat Capacity (c) and Specific Latent Heat (L), and calculate the heat required to melt 0.5 kg of ice at 0°C (L_f = 3.36 × 10⁵ J/kg). | Specific heat capacity (Q = mcΔθ) is the heat required to raise the temperature of 1 kg of a substance by 1 K (with temperature change, no phase change). Specific latent heat (Q = mL) is the heat required to change the state of 1 kg of a substance at constant temperature. For 0.5 kg of ice: Q = mL_f = 0.5 × 3.36 × 10⁵ = 1.68 × 10⁵ J (168 kJ). | ||
| 5 | In JAMB/WAEC Electromagnetism, state the Transformer Voltage/Turns Ratio equation and list the 4 causes of energy loss in a practical transformer with their remedies. | Transformer equation: E_s / E_p = N_s / N_p = I_p / I_s (for 100% ideal transformer). Four energy losses & remedies: 1. Eddy currents -> Laminated soft-iron core; 2. Hysteresis loss -> Soft-iron core (easily magnetized/demagnetized); 3. Copper (I²R Joule heating) loss -> Thick low-resistance copper windings; 4. Flux leakage -> Winding secondary coils over primary on a closed core. | ||
| 6 | In JAMB/WAEC Stoichiometry, what volume does 1 mole of any ideal gas occupy at Standard Temperature and Pressure (STP: 0°C / 273 K and 1 atm / 760 mmHg), and what is Avogadro's constant? | Molar volume at STP = 22.4 dm³ (22,400 cm³); Avogadro's constant (NA) = 6.02 × 10²³ particles per mole. | ||
| 7 | In JAMB/WAEC Electrolysis, what factors determine the preferential discharge of ions at the electrodes during electrolysis of aqueous solutions? | 1. Position of the ion in the Electrochemical Series (lower cations/anions are discharged first), 2. Concentration of the ions (high concentration of halide ion like Cl⁻ in brine overrides OH⁻), and 3. Nature of the electrode (e.g., mercury cathode discharges Na⁺ in the Castner-Kellner cell; reactive copper anode dissolves instead of discharging anions). | ||
| 8 | In JAMB/WAEC Optics, state the Mirror/Lens Equation and Snell's Law of Refraction, and state the two conditions required for Total Internal Reflection (TIR). | Mirror/Lens equation: 1/f = 1/u + 1/v (Magnification M = v/u = h_i/h_o). Snell's Law: n = sin i / sin r = real depth / apparent depth = 1 / sin C (where C is the critical angle). Conditions for TIR: 1. Light must travel from an optically denser medium to an optically less dense medium, and 2. The angle of incidence in the denser medium must exceed the critical angle (i > C). | ||
| 9 | In JAMB/WAEC Radioactivity, if a radioactive isotope has a half-life (T_1/2) of 5 days, what fraction and mass of an initial 80 g sample remain undecayed after 20 days? | Number of half-lives n = 20 / 5 = 4 half-lives. Remaining fraction = (1/2)^n = (1/2)⁴ = 1/16. Remaining undecayed mass = 80 g / 16 = 5 g (meaning 75 g has decayed). | ||
| 10 | In JAMB/WAEC Atomic & Quantum Physics, state Einstein's Photoelectric Equation and define Work Function (W0) and Threshold Frequency (f0). | Einstein's Photoelectric Equation: E = hf = W0 + K_max (where hf = hf0 + ½mv_max²). Work function W0 = hf0 is the minimum energy required to liberate a photoelectron from a metal surface; Threshold frequency f0 is the minimum frequency of incident radiation below which no photoelectric emission occurs regardless of intensity. | ||
| 11 | In JAMB/WAEC Chemical Equilibrium (Le Chatelier's Principle), in the exothermic Haber Process N2(g) + 3H2(g) ⇌ 2NH3(g) (ΔH = -92 kJ/mol), what conditions maximize the yield of ammonia, and what catalyst is used? | High pressure (200–250 atm, since forward reaction reduces moles from 4 to 2), moderate temperature (~450°C—low enough to favor exothermic forward yield, high enough for reaction rate), finely divided Iron (Fe) catalyst with Al2O3 promoter, and continuous removal of NH3. | ||
| 12 | In JAMB/WAEC Mechanics (Elasticity), state Hooke's Law and give the formula for elastic potential energy stored in a stretched spring or wire. | Hooke's Law states that provided the elastic limit is not exceeded, the extension (e) of an elastic material is directly proportional to the applied force/load (F = ke). Elastic potential energy stored E = ½ Fe = ½ ke². | ||
| 13 | In JAMB/WAEC Mechanics (Simple Machines), how are Mechanical Advantage (MA), Velocity Ratio (VR), and Efficiency (η) related, and what is the VR of an inclined plane of angle θ and a block-and-tackle pulley system with n pulleys? | Efficiency η = (MA / VR) × 100%, where MA = Load / Effort and VR = Distance moved by Effort / Distance moved by Load. For an inclined plane, VR = 1 / sin θ; for a block-and-tackle pulley system with n pulleys, VR = n. | ||
| 14 | In JAMB/WAEC Organic Chemistry, what reagents distinguish saturated Alkanes from unsaturated Alkenes and terminal Alkynes? | Unsaturated alkenes and alkynes decolourize reddish-brown Bromine water (Br2/CCl4) and purple acidified KMnO4 (Baeyer's reagent), whereas alkanes do not. Terminal alkynes (containing -C≡C-H) additionally react with ammoniacal Copper(I) chloride to give a reddish-brown precipitate and with ammoniacal Silver trioxonitrate(V) (Tollens' reagent) to give a white/yellow-white precipitate; alkenes do not. | ||
| 15 | In JAMB/WAEC Gas Laws, state Graham's Law of Diffusion and calculate the relative rate of diffusion of Hydrogen gas (M = 2) compared to Oxygen gas (M = 32). | Graham's Law states that at constant temperature and pressure, the rate of diffusion of a gas is inversely proportional to the square root of its vapour density or molar mass: R1/R2 = √(M2/M1). For H2 and O2: R(H2)/R(O2) = √(32/2) = √16 = 4 (Hydrogen diffuses 4 times faster than Oxygen). | ||
| 16 | In JAMB/WAEC Qualitative Analysis, how do you test for and distinguish between Iron(II) (Fe²⁺), Iron(III) (Fe³⁺), Copper(II) (Cu²⁺), and Zinc (Zn²⁺) ions using NaOH(aq) and NH3(aq)? | Fe²⁺: dirty-green gelatinous precipitate insoluble in excess NaOH and NH3; Fe³⁺: reddish-brown precipitate insoluble in excess NaOH and NH3; Cu²⁺: pale blue precipitate insoluble in excess NaOH, but dissolves in excess NH3 to form a deep blue solution; Zn²⁺: white gelatinous precipitate soluble in BOTH excess NaOH and excess NH3. | ||
| 17 | In JAMB/WAEC Alternating Current (AC) Circuits, what is the Impedance (Z) of a series R-L-C circuit, and what is the condition for Resonance? | Impedance Z = √[R² + (X_L - X_C)²], where Inductive reactance X_L = 2πfL and Capacitive reactance X_C = 1 / (2πfC). Resonance occurs when X_L = X_C, making impedance minimum (Z = R), current maximum, and resonant frequency f0 = 1 / [2π√(LC)]. | ||
| 18 | In JAMB/WAEC Radioactivity, how do Alpha (α) decay, Beta (β⁻) decay, and Gamma (γ) emission alter the mass number (A) and atomic number (Z) of a parent nucleus? | Alpha decay (⁴₂He nucleus): A decreases by 4, Z decreases by 2. Beta-minus decay (⁰₋₁e electron from neutron -> proton + electron): A remains unchanged, Z increases by 1. Gamma emission (high-frequency electromagnetic photon): neither A nor Z changes. | ||
| 19 | In JAMB/WAEC Water Chemistry, what causes Temporary Hardness versus Permanent Hardness of water, and how is each removed? | Temporary hardness is caused by dissolved calcium or magnesium hydrogen trioxocarbonate(IV) [Ca(HCO3)2, Mg(HCO3)2] and is removed by boiling or adding slaked lime [Ca(OH)2]. Permanent hardness is caused by dissolved CaSO4, MgSO4, or chlorides and cannot be removed by boiling—it requires washing soda (Na2CO3), caustic soda (NaOH), permutit/ion-exchange resin, or distillation. | ||
| 20 | In JAMB/WAEC Chemical Bonding, why does water (H2O, molar mass 18) have a much higher boiling point (100°C) than hydrogen sulphide (H2S, molar mass 34, gas at room temperature)? | Because H2O molecules form strong intermolecular Hydrogen Bonds (due to the high electronegativity of oxygen), whereas H2S molecules only have weak van der Waals (dipole-dipole) forces. | ||
| 21 | In JAMB/WAEC Physics (Dimensions & Units), what are the fundamental SI units and dimensional formulas for Force, Work/Energy, Power, Pressure, and Momentum? | Force: Newton (N), [MLT⁻²]; Work/Energy: Joule (J), [ML²T⁻²]; Power: Watt (W), [ML²T⁻³]; Pressure/Stress/Young's Modulus: Pascal (Pa = N/m²), [ML⁻¹T⁻²]; Linear Momentum/Impulse: kg·m/s (N·s), [MLT⁻¹]. | ||
| 22 | In JAMB/WAEC Kinematics & Projectile Motion, what are the formulas for Time of Flight (T), Maximum Height (H), and Horizontal Range (R) of a projectile launched at speed u and angle θ to the horizontal, and at what angle is Range maximum? | Time of flight T = (2u sin θ) / g; Maximum height H = (u² sin² θ) / (2g); Horizontal Range R = (u² sin 2θ) / g. Maximum horizontal range R_max = u²/g occurs when θ = 45° (since sin 90° = 1). | ||
| 23 | In JAMB/WAEC Electrostatics, how is the equivalent capacitance calculated for Capacitors in Parallel versus Capacitors in Series, and what is the energy stored in a capacitor? | Note that capacitors combine OPPOSITE to resistors: In Parallel: C_eq = C1 + C2 + C3; In Series: 1/C_eq = 1/C1 + 1/C2 + 1/C3. Energy stored W = ½ QV = ½ CV² = ½ Q²/C. | ||
| 24 | In JAMB/WAEC Organic Chemistry, what are the products of oxidation of a Primary (1°), Secondary (2°), and Tertiary (3°) alkanol with acidified K2Cr2O7 or KMnO4? | Primary alkanol (R-CH2OH) oxidizes first to an Alkanal (aldehyde) and on further oxidation to an Alkanoic acid (carboxylic acid). Secondary alkanol (R2CHOH) oxidizes to an Alkanone (ketone) only. Tertiary alkanol (R3COH) resists oxidation. | ||
| 25 | In JAMB/WAEC Chemistry, which separation technique is used to separate: (a) crude oil fractions, (b) ink dyes, (c) ammonium chloride from NaCl, and (d) immiscible liquids (kerosene and water)? | (a) Fractional distillation (based on close boiling points), (b) Chromatography (differential migration/adsorption), (c) Sublimation (NH4Cl, I2, camphor, and dry ice sublime directly from solid to gas), and (d) Separating funnel (immiscible liquids of different densities). | ||
| 26 | In JAMB/WAEC Industrial Chemistry, name the industrial process and catalyst used to manufacture: (a) H2SO4, (b) HNO3, (c) Sulphur extraction, and (d) Aluminium extraction. | (a) H2SO4: Contact Process using Vanadium(V) oxide (V2O5) catalyst; (b) HNO3: Ostwald Process using Platinum-Rhodium gauze catalyst; (c) Sulphur: Frasch Process (superheated water & hot compressed air through 3 concentric pipes); (d) Aluminium: Hall-Héroult electrolysis of purified Bauxite (Al2O3) dissolved in molten Cryolite (Na3AlF6). | ||
| 27 | In JAMB/WAEC Fluid Mechanics, state Archimedes' Principle and the Law of Flotation. | Archimedes' Principle: When a body is wholly or partially immersed in a fluid, it experiences an upward thrust (upthrust) equal to the weight of the fluid displaced. Law of Flotation: A floating body displaces its own weight of the fluid in which it floats. | ||
| 28 | In JAMB/WAEC Physics (Circular & Simple Harmonic Motion), what is the period (T) of a simple pendulum of length L, and how does the period change if its length is quadrupled (4L) or the bob's mass is doubled? | Period T = 2π√(L/g). Period is independent of the mass of the bob; if length L is quadrupled (4L), the period T doubles (√4 = 2). | ||
| 29 | In JAMB/WAEC Organic Chemistry, what is Esterification versus Saponification? | Esterification is the reversible reaction between an alkanol (alcohol) and an alkanoic (carboxylic) acid in the presence of concentrated H2SO4 catalyst to form a sweet-smelling ester and water. Saponification is the alkaline hydrolysis of fats/oils (triacylglycerols) by boiling with NaOH or KOH to produce soap (sodium/potassium salt of fatty acids) and propane-1,2,3-triol (glycerol). | ||
| 30 | In JAMB/WAEC Electrochemistry, state Faraday's First Law of Electrolysis and calculate the mass of copper (Cu = 64) deposited when a current of 2.0 A flows through CuSO4(aq) for 965 seconds (1 F = 96,500 C). | Faraday's First Law: Mass deposited (m) is directly proportional to quantity of electricity Q = It. For Cu²⁺ + 2e⁻ -> Cu, 2 Faradays (2 × 96,500 C) deposit 64 g of Cu. Here Q = 2.0 × 965 = 1,930 C. Mass m = (64 × 1,930) / (2 × 96,500) = 0.64 g. | ||
| 31 | In JAMB/WAEC Chemistry (Redox & Oxidation Numbers), what is the oxidation number of Chromium in K2Cr2O7 and Manganese in KMnO4? | In K2Cr2O7: 2(+1) + 2x + 7(-2) = 0 => 2x = 12 => x = +6 [Tetraoxochromate(VI) / Heptaoxodichromate(VI)]. In KMnO4: (+1) + x + 4(-2) = 0 => x = +7 [Tetraoxomanganate(VII)]. | ||
| 32 | In JAMB/WAEC Current Electricity, how is a Galvanometer of resistance Rg and full-scale deflection current Ig converted into: (a) an Ammeter to read up to current I, and (b) a Voltmeter to read up to voltage V? | (a) To convert to an Ammeter, connect a low-resistance SHUNT resistor (R_s) in PARALLEL with the galvanometer: Ig·Rg = (I - Ig)·R_s. (b) To convert to a Voltmeter, connect a high-resistance MULTIPLIER resistor (R_m) in SERIES with the galvanometer: V = Ig(Rg + R_m). |